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"I'm really not pushing myself that I have to win here.
I just think that I'll probably try next time and if I win, great.
Martinez progressed with a win over Patty Schnyder.
Jana Novotna, the reigning champion and No 5 seed here, made short work of beating the 21-year-old Sylvia Plischke of Austria, who is ranked No 27.
Schnell will battle Torrens-Vallero inthe second round.
Jelena Kostanic of Croatia knocked off Anna Zarska of Poland, 6-4, 6-3. American Jennifer Hopkins beat qualifier Dessislava Topalova of Bulgaria, 7-5, 6-2, but will have a tougher time against seventh seed Patricia Wartusch of Austria, who needed three sets to defeat Miroslava Vavrinec of Switzerland on Monday.
Garbin's second-round opponent will be qualifier Libuse Prusova of the Czech Republic, who beat Maria Antonia Sanchez Lorenzo of Spain, 7-5, 6-4.
In the second round Boogert faces Slovakia's Henrieta Nagyova who won on Monday. 6 Adriana Gersi of the Czech Republic also advanced Tuesday with a straight-set victory over Belgian Laurence Courtois, 6-3, 6-4.
Defending champion and unseeded Cristina Torrens-Valero of Spain knocked off top seeded Elena Likhovtseva of Russia Tuesday at the claycourt Warsaw Open. 2 Kristina Brandi of the United States was eliminated on Monday, Likhovtseva also made an early exit, losing 4-6, 6-3, 6-4 to Torrens-Valero.
Third seed Tathiana Garbin of Italy is the highest remaining seed after overcoming Australian Annabel Ellwood, 4-6, 6-4, 6-1.
She has twice reached the final and lost, in 19, both times against Steffi Graf.
Would she come back to SW19 for another shot next year?