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The racial makeup of the city was 83% White, 5.4% African American, 1.4% Indigenous American, 1.7% Asian, 0.02% Pacific Islander, 11.3% from other races, and 2.6% from two or more races.Hispanics or Latinos of any race were 38.5% of the population.The Santa Fe Railroad arrived in 1888 and the Kansas City, Mexico and Orient Railway in 1909.

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During the colonization of the region, San Angelo was at the western edge of the region called Texas, successively claimed in the 1800s by the nations of Spain, Mexico, the Republic of Texas, and finally the United States, in 1846.The current city of San Angelo was founded in 1867, when the United States built Fort Concho, one of a series of new forts designed to protect the frontier.The fort was home to cavalry, infantry, and the famous Black Cavalry, also known as Buffalo Soldiers by Indigenous Americans. De Witt founded the village of Santa Angela outside the fort at the junction of the North and South Concho Rivers.San Angelo grew exponentially during the oil boom of the 1900s, when vast amounts of oil were found in the area, and the city became a regional hub of the oil and gas industry.According to the United States Census Bureau, the city has a total area of 58.2 square miles (150.9 km²), of which, 55.9 square miles (144.8 km²) is land and 2.3 square miles (6.1 km²) (4.03%) is covered by water.

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